Benzotriazol-1-ylmethyl isocyanide, a new synthon for CH-N=C transfer. Syntheses of α-hydroxyaldehydes, 4-ethoxy-2-oxazolines and oxazoles

DOI: 10.1016/S0040-4039(00)70643-5

Source and publish data:

Tetrahedron Letters p. 6657 - 6660 (1989)

Update date:2022-08-11

Topics:

Authors:

Katritzky

Chen Chen

Yannakopoulou

Lue Lue

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Article abstract of DOI:10.1016/S0040-4039(00)70643-5

Readily prepared benzotriazol-1-ylmethyl isocyanide (BetMIC) reacts under mild conditions with ketones and aldehydes, to afford oxazolines (convertible into α-hydroxyaldehydes) and oxazoles, respectively.

Full text of DOI:10.1016/S0040-4039(00)70643-5

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