A Barbier allylation and a Reformatsky reaction of carbonyl compounds mediated by indium(I) iodide

DOI: 10.1016/0022-328X(89)85180-0

Source and publish data:

Journal of Organometallic Chemistry p. 291 - 296 (1989)

Update date:2022-08-12

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Authors:

Araki, Shuki

Ito, Hirokazu

Katsumura, Nobuhito

Butsugan, Yasuo

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Article abstract of DOI:10.1016/0022-328X(89)85180-0

Indium(I) iodide was found to mediate in the Barbier allylation and in the Reformatsky reaction of aldehydes and ketones to give homoallylic alcohols and β-hydroxy esters, respectively, presumably via allylindium(III) diiodide.

Full text of DOI:10.1016/0022-328X(89)85180-0

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