Platinum complex catalyzed carbonylative cross-coupling of alkyl iodides with sodium tetraphenylborate; synthesis of alkyl phenyl ketones

DOI: 10.1016/0022-328X(88)80102-5

Source and publish data:

Journal of Organometallic Chemistry p. 397 - 404 (1988)

Update date:2022-08-28

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Authors:

Kondo, Teruyuki

Tsuji, Yasushi

Watanabe, Yoshihisa

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Article abstract of DOI:10.1016/0022-328X(88)80102-5

Tetrakis(triphenylphosphine)platinum(0) (Pt(PPh3)4) is an effective catalyst precursor for the carbonylative cross-coupling of alkyl iodides with sodium tetraphenylborate (NaBPh4) which yields the corresponding alkyl phenyl ketones.In the reaction of n-hexyl iodide with NaBPh4, n-hexyl phenyl ketone was obtained in 60percent yield.

Full text of DOI:10.1016/0022-328X(88)80102-5

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