Endo-Selective Insertion by Norcaranylidene Carbenoid into the α-C-H Bond of Alkoxides: Evidence of a Hydride Abstraction-Recombination Mechanism

DOI: 10.1021/jo00369a041

Source and publish data:

Journal of Organic Chemistry p. 3730 - 3732 (1986)

Update date:2022-08-15

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Authors:

Oku, Akira

Yamaura, Yasunari

Harada, Toshiro

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Article abstract of DOI:10.1021/jo00369a041

A hydride abstraction-recombination mechanism in the insertion of the α-C-H bond of alkoxides by norcaranylidene carbenoid is proposed on the basis of the preferential endo stereoselectivity at the carbenic carbon of the insertion products

Full text of DOI:10.1021/jo00369a041

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