Tetrahedron Letters p. 2945 - 2948 (1989)
Update date:2022-08-29
Topics:
Kusuda, Kazuhiro
Junji, Inanaga
Yamaguchi, Masaru
A variety of α-oxygenated esters, such as α-acetoxy, α-methoxy-, α-OTPH, and α-hydroxy esters were easily reduced at room temperature to give the corresponding saturated esters in good to excellent yields with the aid of an efficient electron transfer system, SmI2-THF-HMPA.The method was succesfully applied to the direct conversion of (R,R)-tartrates to (R)-malates.
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