TRIMETHYLSILYLFLUOROSULFONATE (TMSOFs): AN ALTERNATIVE TO TMS TRIFLATE AS A SOURCE OF Me3Si+

DOI: 10.1016/S0040-4039(00)77474-0

Source and publish data:

Tetrahedron Letters p. 995 - 998 (1993)

Update date:2022-08-18

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Authors:

Lipshutz, Bruce H.

Burgess-Henry, Jana

Roth, Gregory P.

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Article abstract of DOI:10.1016/S0040-4039(00)77474-0

Generation of trimethylsilylfluorosulfonate in situ provides a useful source of TMS⁺, the reactivity of which is essentially equivalent to that of TMS triflate.Its precursors, in particular FSO3H, are less costly than those of TMSOTf or the reagent itself.

Full text of DOI:10.1016/S0040-4039(00)77474-0

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