Journal of the Chemical Society. Chemical communications p. 574 - 575 (1980)
Update date:2022-08-16
Topics:
Triebe, F. M.
Hawley, M. Dale
McDonald, Richard N.
Diazoalkane anion radicals produced by electroreduction of diazodiphenylmethane (Ph2CN2) and 9-diazofluorene (FlN2) in the presence of certain proton donors yield the corresponding hydrazones (R2C=NNH2); formation of diphenylmethane from electroreduction of Ph2CN2 is shown to proceed by formation of the carbene anion radical Ph2C*-.
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