Bull. Russ. Acad. Sci. Div. Chem. Sci. (Engl. Transl.) p. 1497 - 1499 (1992)
Update date:2022-08-17
Topics:
Kolomnikova, G. D.
Prikhodchenko, D. Yu.
Petrovskii, P. V.
Golobov, Yu. A.
α-Cyanoacrylic acid and α-cyanoacrylates add dialkyl and diaryl phosphites and diethyl thiophosphite at the C=C double bond in the absence of catalyst.This is an anti-Markpvnikov reaction, which yields the corresponding phosphonates and thiophosphonates. Keywords: alkenes, hydrophosphorylation, addition reaction, thiophosphites, thiophosphonates, phosphites, phosphonates, cyanoacrylic acid.
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