Journal of the American Chemical Society p. 2400 - 2405 (1986)
Update date:2022-08-05
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Mitsuhashi, Tsutomu
The first example of the azo Cope rearrangement is presented.Arylazo(α,α-dimethylallyl)malononitriles are readily rearranged to N-(γ,γ-dimethylallyl)arylhydrazonomalononitriles under mild conditions.The reaction rate increases greatly with increasing elec
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