Tetrahedron p. 3007 - 3034 (1993)
Update date:2022-08-11
Topics:
Peter, Andrew
Vaughan-Williams, Gina F.
Rosser, Richard M.
Dimesitylboron stabilised carbanions react with oxiranes to give products that can be oxidised to 1,3-diols. The reactions are, in general, under steric rather than electronic control, and proceed smoothly for all but tetrasubstituted oxiranes. Some unusual stereoselective effects have been observed.
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