ACTIVATED METALLIC NICKEL IN PREPARATION OF SYMMETRICAL 1,3-DIARYLPROPAN-2-ONES FROM BENZYLIC HALIDES AND OXALYL CHLORIDES

DOI: 10.1246/cl.1984.25

Source and publish data:

Chemistry Letters p. 25 - 28 (1984)

Update date:2022-08-25

Topics:

Authors:

Inaba, Shin-ichi

Rieke, Reuben D.

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Article abstract of DOI:10.1246/cl.1984.25

Oxidative addition of benzylic halides to nickel in the metallic state followed by insertion of carbon monoxide generated from alkyl oxalyl chlorides proceeded smoothly to give symmetrical 1,3-diarylpropan-2-ones in moderate yields.

Full text of DOI:10.1246/cl.1984.25

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