Oxidation of Alcohols with Peracetic Acid in Ethyl Acetate in the Presence of Sodium Bromide

DOI: 10.1246/bcsj.65.703

Source and publish data:

Bulletin of the Chemical Society of Japan p. 703 - 706 (1992)

Update date:2022-08-11

Topics:

Authors:

Morimoto, Takashi

Hirano, Masao

Hamaguchi, Takayoshi

Shimoyama, Masahide

Zhuang, Xiumin

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Article abstract of DOI:10.1246/bcsj.65.703

Aliphatic primary alcohols and 1,ω-diols were oxidized to the dimeric esters and lactones, respectively, by peracetic acid in ethyl acetate in the presence of sodium bromide under mild conditions.Aliphatic secondary and benzylic alcohols were converted smoothly to the corresponding carbonyl compounds by the same system.

Full text of DOI:10.1246/bcsj.65.703

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