Journal of Organometallic Chemistry p. 175 - 179 (1990)
Update date:2022-08-11
Topics:
Zakrzewski, Janusz
Giannotti, Charles
A new synthesis of azaferrocene, (η5-C4H4N)(η5-C5H5)Fe, involving photo-substitution of iodide in (η5-C5H5)Fe(CO)2I by the η1-pyrrolyl ligand, followed by decarbonylation of the resulting dicarbonyl η1-pyrrolyl complex, is described.The mechanism of the former reaction is discussed in terms of the photo-induced SRN1-type chain process.
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