Extraction of Highly Hydrophilic Anions in Low Polarity Media under Phase-transfer Catalysis Conditions: Dramatic Enhancement of the OH- Reactivity by Reduction of its Specific Hydration

DOI: 10.1039/c39840001041

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1041 - 1042 (1984)

Update date:2022-08-10

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Authors:

Landini, Dario

Maia, Angelamaria

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Article abstract of DOI:10.1039/c39840001041

In the chlorobenzene-aqueous NaOH two-phase system, an increase in NaOH concentration from 5 to 20 M reduces the OH- hydration sphere of the tetrahexylammonium hydroxide (1a) dissolved in chlorobenzene from 11 to 3.5 molecules of water, thus producing a dramatic increase (up to 10⁴ times) in OH- reactivity.

Full text of DOI:10.1039/c39840001041

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