Green Chemistry p. 3450 - 3456 (2018)
Update date:2022-08-17
Topics:
Fan, Yonghui
Li, Shenggang
Bao, Jingxian
Shi, Lei
Yang, Yanzhang
Yu, Fei
Gao, Peng
Wang, Hui
Zhong, Liangshu
Sun, Yuhan
A green strategy was developed for the synthesis of various value-added chemicals using methanol, acetonitrile, acetic acid, acetone and ethyl acetate as the hydrogen source by coupling them with olefins over heterogeneous photocatalysts. A radical coupling mechanism was proposed for the hydrofunctionalization of olefins with methanol to higher aliphatic alcohols over the Pt/TiO2 catalyst as the model reaction. C-H bond cleavage and C-C bond formation between photogenerated radicals and terminal olefins were accomplished in a single reaction at high efficiency. Our approach is atomically economical with high anti-Markovnikov regioselectivity and promising application potential under mild reaction conditions.
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