Electrochemical Epoxidation of Electron-Poor Olefins Using Silver Bipyridine Based Redox Mediators

DOI: 10.1016/S0040-4039(00)73074-7

Source and publish data:

Tetrahedron Letters p. 3695 - 3698 (1994)

Update date:2022-08-11

Topics:

Authors:

Kandzia, Christof

Steckhan, Eberhard

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Article abstract of DOI:10.1016/S0040-4039(00)73074-7

Electrogenerated and regenerated silver(III)oxo bis(2,2'-bipyridine) and similar complexes can act as redox catalysts for the indirect electrochemical epoxidation of electron-deficient olefins in aqueous acetonitrile.Thus, isobutyl methacrylate is electrolyzed to form the epoxide with 87percent material yield and 21percent current yield.

Full text of DOI:10.1016/S0040-4039(00)73074-7

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