Journal of the Chemical Society. Chemical communications p. 1918 - 1919 (1989)
Update date:2022-08-17
Topics:
Lubineau, Andre
Bienayme, Hugues
Gallic Le, Joelle
α-Linked spacer arms, suitable for coupling on a protein carrier, have been introduced directly on GlcNAc and on Gal-β(1-3)GalNAc in a 1,2-cis fashion through a new procedure involving a completely stereoselective Michael addition of the anomeric sodium alcoholate onto β-tosyloxy acrolein prepared in situ from the sodium salt of malonaldehyde and tosyl chloride.
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