A novel reducing agent. The reduction of dicarbonyls, acyloins, alkynes, and alkenes with active uranium

DOI: 10.1016/0022-328X(88)80144-X

Source and publish data:

Journal of Organometallic Chemistry p. C45 - C48 (1988)

Update date:2022-08-17

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Authors:

Kahn, Bruce E.

Rieke, Reuben D.

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Article abstract of DOI:10.1016/0022-328X(88)80144-X

Active uranium, prepared in hydrocarbon solvents from UCl4 and <(TMEDA)Li>2 is a novel reducing agent.The unprecedented stepwise reduction of benzil and benzoin to bibenzyl has been shown to proceed via the unsaturated species diphenylacetylene, cis-stilbene, and trans-stilbene.Active uranium also effects oligomerizations of diphenylacetylene and trans-stilbene.

Full text of DOI:10.1016/0022-328X(88)80144-X

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