Journal of Organometallic Chemistry p. 277 - 284 (1980)
Update date:2022-08-11
Topics:
Uemura, Sakae
Wakasugi, Mikio
Okano, Masaya
Aryltellurium(IV) compounds react with olefins to give the corresponding arylated olefins in moderate to quantitative yield in the presence of a palladium(II) salt.The reaction proceeds catalytically with respect to the palladium(II) salt if a suitable oxidant, such as t-butyl hydroperoxide or copper(I) or (II) chloride, is added.In the absence of olefin the corresponding biaryls are formed in moderate yield.Transmetalation of tellurium with palladium is a key step of the reaction.
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