Journal of the American Chemical Society p. 4916 - 4922 (1984)
Update date:2022-08-16
Topics:
Buchwald, Stephen L.
Pliura, Diana H.
Knowles, Jeremy R.
The phosphoro group of 2-phosphoropropane-1,2-diol migrates to the 1-position on heating in aqueous acid.This migration occurs by two routes.The direct route is belived to proceed via a pentacoordinate intermediate that must, by Westheimer's rules, pseudo
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