Tetrahedron Asymmetry p. 367 - 370 (1997)
Update date:2022-08-11
Topics:
Miyazawa, Toshifumi
Minowa, Hiroe
Miyamoto, Toyoko
Imagawa, Kiwamu
Yanagihara, Ryoji
Yamada, Takashi
In the microbial protease-catalyzed hydrolysis of amino acid esters with the free α-amino group, the enantioselectivity can be enhanced greatly by employing esters with longer alkyl chains such as the isobutyl ester instead of the conventional methyl ester and by conducting the reaction at low temperature.
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