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Selectivity in palladium catalyzed arylation: Synthetic application leading to aromatized ionone natural products

DOI: 10.1016/S0040-4039(98)00657-1

Source and publish data:

Tetrahedron Letters p. 4055 - 4058 (1998)

Update date:2022-08-16

Topics:

Authors:

Hagiwara, HisahiroHagiwara, Hisahiro

Eda, YasushiEda, Yasushi

Morohashi, KimieMorohashi, Kimie

Suzuki, ToshioSuzuki, Toshio

Ando, MasayoshiAndo, Masayoshi

Ito, NobuhikoIto, Nobuhiko

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Article abstract of DOI:10.1016/S0040-4039(98)00657-1

The selectivity in aromatic substitution vs conjugate addition during palladium catalyzed reactions has been controlled simply by changing the base. These reaction conditions have been applied to the syntheses of aromatized β-ionone natural products 1 and its dihydroderivatives 7.

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Full text of DOI:10.1016/S0040-4039(98)00657-1

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