Chemistry Letters p. 1763 - 1766 (1981)
Update date:2022-08-28
Topics:
Kaneda, Kiyotomi
Yasumura, Morito
Hiraki, Masahiko
Imanaka, Toshinobu
Teranishi, Shiichiro
α-olefins are carbonylated to give corresponding alcohols under mild water gas shift reaction (WGSR) conditions using Rh6(CO)16-N,N,N',N'-tetramethyl-1,3-propanediamine and 4-dimethylaminopyridine catalyst systems. α,β-Unsaturated carbonyl compounds give selectively C=C reduction products.
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