Cyanation and Nitration of Toluene with Cyanamide and Nitramide through Intermediate Cyano- and Nitrodiazonium Ions. Attempted Fluorination of Aromatics with Fluorodiazonium Ion

DOI: 10.1021/jo00208a049

Source and publish data:

Journal of Organic Chemistry p. 1338 - 1339 (1985)

Update date:2022-08-29

Topics:

Authors:

Olah, George A.

Laali, Khosrow

Farnia, Morteza

Shih, Joseph

Singh, Brij P.

et al. et al.

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Article abstract of DOI:10.1021/jo00208a049

Toluene is cyanated and nitrated with cyano- and nitrodiazonium ion, generated via in situ diazotization of cyanamide and nitramide, respectively, with NO⁺BF4^-.Attempted fluorination with fluorodiazonium ion, prepared from cis-difluorodiazene and arsenic pentafluoride, gave only trace amounts of fluoroaromatics.

Full text of DOI:10.1021/jo00208a049

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