Catalysis Communications p. 31 - 35 (2017)
Update date:2022-08-11
Topics:
Xu, Yong
Lv, Xiao-Jun
Chen, Yong
Fu, Wen-Fu
We developed a new strategy for the efficient reduction of nitroarenes using sodium sulfide as reducing agent with MOF-derived Co3S4 as catalyst in water and at room temperature. The introduction of sodium sulfite enhanced the reactant conversion and product selectivity, and the as-synthesized catalyst was used repeatedly five times and retained its activity and selectivity. A wide spectrum of reducible functional moieties kept unaffected under the reaction conditions, and isotope labeling experiment showed the hydrogen atom was derived from water.
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Doi:10.1021/jo972183m
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