Journal of Organic Chemistry p. 3861 - 3864 (1986)
Update date:2022-07-30
Topics:
Laurent, Denis R. St.
Paquette, Leo A.
2-(2,2-Diethoxyethyl)-1,3-dithiane (5) in its anionic form undergoes Michael addition to 2-cyclopentenone.Acid hydrolysis of the adduct gives rise to the pair of epimeric diquinane aldols 9 and 10 as well as 11 in ratios that are sensitive to both acid co
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