Page 5 of 7
ACS Catalysis
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1486-1495.
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ciently underwent C-O activation to form the desired biaryl 3
on treatment with 2b.
1
2
3
4
5
6
7
8
(10) Only report is the reaction of o-2-benzofuryl aryl carba-
mate with 2.5 equiv of phenyl boronic acid to afford 21% yield in o-
xylene at 150 °C [Quasdorf, K. W.; Antoft-Finch, A.; Liu, P.; Silber-
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N.; Snieckus, V.; Garg, N. K. J. Am. Chem. Soc. 2011, 133, 6352-
6363].
CONCLUSIONS
This work describes the ensembling catalysis by Ni-Pd bina-
ry NCs for C-O bond activation for Suzuki-Miyaura cross-
coupling of o-heterocycle-tethered sterically hindered aryl
ester, silyl ether, sulfonates, carbamate, and carbonates with
aryl boronic acids. The catalyst system comprising of Ni-Pd
binary NCs is distinctly superior to the various Pd/Ni com-
pounds/complexes reported for Suzuki-Miyaura cross-
coupling reaction involving phenol-based electrophilic cou-
pling partner. The inability of the individual Ni and Pd NPs to
promote the Suzuki-Miyaura cross-coupling of the o-
heterocycle-tethered electrophilic coupling partners imply a
co-operative effect of the Ni and Pd NPs in the Ni-Pd NCs.
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ASSOCIATED CONTENT
Supporting Information. Experimental procedures, spectral data,
and scanned spectra available free of charge via the Internet at
Corresponding Author
* akchakraborti@niper.ac.in; akchakraborti@rediffmail.com
Author Contributions
The manuscript was written through contributions of all authors.
All authors have given approval to the final version of the manu-
script.
Authors thank CSIR (senior research fellowship to KS) and DST
(SR/S1/OC-33/2008), New Delhi, India for Financial support.
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