-Wittig Rearrangement of 13-Membered Diallylic Ethers, Six-Step Synthesis of Costunolide

DOI: 10.1021/jo00372a047

Source and publish data:

Journal of Organic Chemistry p. 4315 - 4316 (1986)

Update date:2022-08-11

Topics:

Authors:

Takahashi, Takashi

Nemoto, Hisao

Kanda, Yutaka

Tsuji, Jiro

Fujise, Yutaka

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00372a047

The stereoselective synthesis of costunolide using <2,3>-Wittig rearrangement of 13-membered diallylic ethers and discussion for diastereoselectivity are presented.

Full text of DOI:10.1021/jo00372a047

Products guided by the article

Product name:(1S,2S,3S,6S)-3-methyl-2,6-di(prop-1-en-2-yl)-3-vinylcyclohexan-1-ol

Cas No:104423-10-1

R&D Labs maybe for 104423-10-1

He Bei Shun Er Chemical Co., LTD.

Contact:86-0311-86996932/86860168

Address:No 18,North street
Zipont chem(wuhan）Tech co.，Ltd

Contact:+86-27-87587198

Address:wuhan
Chengdu D-Innovation Pharmaceutical Co., Ltd

Contact:86-28-85105536

Address:1001, B6, No.88 Keyuan South Road, Chengdu Hi-Tech Zone
Tianjin Crest Pharmaceutical R&D Co., Ltd. （Tianjin Yao Technology Development Co., Ltd.）(expird)

Contact:+86-22-66211386

Address:Building B5-405, No, 80 4th Avenue, TEDA, Tianjin, China P.R. 300457
Nanjing Qirui Material Co., Ltd.

Contact:+86-25-52320053

Address:F4-5, #17 Building, Chuang Yi Yuan, No.6 Guanghua East Street, Nanjing, 210007 P.R.China

Relevant to this article

Doi:10.1016/S0277-5387(00)80801-3
(1987)
Eco-friendly microwave synthesis of Mg(II) phenoxy carboxylic acid coordination compounds with specific motifs driven by multiple hydrogen bonding

Doi:10.1039/c6ra09589e
(2016)
Reductive amidation of nitroarenes: a practical approach for the amidation of natural products

Doi:10.1016/j.tetlet.2009.04.061
(2009)
Doi:10.1021/ja01133a021
()
Doi:10.1007/BF00909407
()
Substituent Effects on the Decomposition of Bis(tert-butylperoxy)cycloalkanes

Doi:10.1021/jo00059a029
(1993)

Article Doi