Tetrahedron p. 7283 - 7292 (1994)
Update date:2022-08-11
Topics:
Calo, Vincenzo
Fiandanese, Vito
Nacci, Angelo
Scilimati, Antonio
Optically active allylic sulphides 10-13, bearing two different leaving groups, react with organocopper reagents by selective substitution of the heterocyclic moiety leading to optically active homoallylic pivalates with chemo-, regio- and enantio-control.This selectivity seems to be related to the coordination exerted by the heterocyclic nucleus towards the organometal.
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