The synthesis of a new palladacycle catalyst. Development of a high performance catalyst for Heck reactions

Article abstract of DOI:10.1016/S0040-4039(99)01514-2

The new palladacycle catalyst 5 was synthesized, and this Pd catalyst showed high catalytic activity with turnover numbers of up to 8 900 000 (mol product per mol Pd) and turnover frequencies of up to 400 000 (mol product per mol Pd per h) in the coupling