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The Chemistry of C6S10: a Channel Structure for C6S10(CS2)0.5 and Access to the Versatile DMAD*C3S4O (DMAD = dimethylacetylenedicarboxylate)

DOI: 10.1039/c39900000034

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 34 - 36 (1990)

Update date:2022-08-16

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Authors:

Yang, XiaoguangYang, Xiaoguang

Rauchfuss, Thomas B.Rauchfuss, Thomas B.

Wilson, ScottWilson, Scott

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Article abstract of DOI:10.1039/c39900000034

Treatment of (Et4N)2 with SO2Cl2 gives molecular C6S10 (1), structurally characterized as (1)*(CS2)0.5, which has a channel structure; a two step conversion affords bicyclic tetrathiaindenone OC3S4*C2(CO2Me)2 which is used to make new alkenedithiolate derivatives.

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