The Role of Titanium and Iron Complexes in the Deoxygenation of Aromatic Nitroso-compounds

DOI: 10.1039/DT9840002577

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2577 - 2580 (1984)

Update date:2022-08-31

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Authors:

Fochi, Giovanni

Floriani, Carlo

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Article abstract of DOI:10.1039/DT9840002577

Deoxygenation of aromatic nitroso-compounds RNO (R = Ph or biphenyl-2-yl) under very mild conditions by titanium(II) and titanium(III) derivatives such as , <2>, (cp = η⁵-C5H5), and TiCl3 led to the formation of oxo-complexes and the corresponding azo- and azoxy-organic compounds.Carbazole was not formed, suggesting a metal-controlled pathway for evolution of the plausible intermediate nitrene.Similar results have been obtained using N,N'-ethylenebis(salicylideneiminato)iron(II), , which was converted into <2O>.

Full text of DOI:10.1039/DT9840002577

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