ABNORMAL PRODUCTS OF PALLADIUM CATALYSED REACTIONS OF (1-BROMOVINYL)TRIMETHYLSILANE

DOI: 10.1016/S0040-4039(01)80497-4

Source and publish data:

Tetrahedron Letters p. 3735 - 3736 (1989)

Update date:2022-08-10

Topics:

Authors:

Ennis, David S.

Gilchrist, Thomas L.

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Article abstract of DOI:10.1016/S0040-4039(01)80497-4

Coupling reactions of (1-bromovinyl)trimethylsilane (1) with organozinc bromides catalyzed by tetrakis(triphenylphosphine)palldium(0) give not only the expected 1-substituted vinylsilanes (2) but also the isomeric 2-substituted vinylsilanes (3).

Full text of DOI:10.1016/S0040-4039(01)80497-4

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