Journal of the Chemical Society. Perkin transactions I p. 2879 - 2884 (1996)
Update date:2022-08-11
Topics:
Aller, Enrique
Buck, Richard T.
Drysdale, Martin J.
Ferris, Leigh
Haigh, David
Moody, Christopher J.
Pearson, Neil D.
Sanghera, J. Bobby
Rhodium(II) acetate-catalysed decomposition of diazophenylacetates 1 and 3 in the presence of a range of N-H compounds results in an N-H insertion reaction of the intermediate carbenoids and formation of N-substituted phenylglycine derivatives 2 and 4. The corresponding reactions of dimethyl α-diazobenzylphosphonate 5 constitute a simple route to aminophosphonates 6.
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