Enantioselective Addition of Diethylzinc to Aldehydes Catalyzed by Polymer-Supported Chiral Amino Alcohols. Evidence for a Two Zinc Species Mechanism.

DOI: 10.1021/jo00227a043

Source and publish data:

Journal of Organic Chemistry p. 4140 - 4142 (1987)

Update date:2022-08-17

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Authors:

Itsuno, Shinichi

Frechet, Jean M.J.

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Article abstract of DOI:10.1021/jo00227a043

Polymer-bound chiral amino alcohols (in particular, (dialkylamino)isoborneol) are excellent heterogeneous recyclable catalysts in the enantioselective alkylation of aromatic aldehydes with dialkylzinc.

Full text of DOI:10.1021/jo00227a043

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