Catalysis Letters p. 1653 - 1662 (2021)
Update date:2022-08-11
Topics:
Moradi, Marjan
Rastakhiz, Nahid
Ghaedi, Mehrorang
Zhiani, Rahele
Abstract: Nitro-aromatic pollution in industrial waste streams threat wellbeing of water resources. This study investigates the performance of a copper-based nano catalyst to reduce nitro-aromatic compounds in aqueous solution. Anchoring Cu NPs within the nano spaces of a fibrous silicate with high surface area, and simple accessibility of active sites were successfully established by a facile approach to produce a novel nanocatalyst (DFNS/PEI/Cu). DFNS displayed different properties such as dandelion-like shape, high surface area, and simple availability of active sites. Immobilization of the Cu NPs on DFNS nanospheres not only prevented their aggregation, but also considerably improved the availability of the catalytic active sites. The DFNS/PEI/Cu nanocatalyst demonstrated great catalytic activities for the reduction of nitro compounds under green conditions. Our findings show fibrous DFNS and Cu NPs as a helpful platform for the fabrication of noble metal-based affordable nanocatalyst for many catalytic applications. Graphic Abstract: DFNS/PEI/Cu nanocatalyst as a new adsorbents for the reduction of nitro compounds[Figure not available: see fulltext.]
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