1560-32-3

Basic information

• Product Name: 10-BROMO-9(10H)-ANTHRACENONE
• Synonyms: 10-BROMO-9(10H)-ANTHRACENONE;10-Bromoanthrone
• CAS NO: 1560-32-3
• Molecular Formula: C₁₄H₉BrO
• Molecular Weight: 273.12466
• Mol File: 1560-32-3.mol
• Article Data: 5

Chemical Properties

• Melting Point: 146-149 °C
• Boiling Point: 354.1°Cat760mmHg
• Flash Point: 81.3°C
• Appearance: /
• Density: 1.543g/cm³
• Vapor Pressure: 3.43E-05mmHg at 25°C
• Refractive Index: 1.673
• CAS DataBase Reference: 10-BROMO-9(10H)-ANTHRACENONE(CAS DataBase Reference)
• NIST Chemistry Reference: 10-BROMO-9(10H)-ANTHRACENONE(1560-32-3)
• EPA Substance Registry System: 10-BROMO-9(10H)-ANTHRACENONE(1560-32-3)

Safety Data

• Hazardous Substances Data: 1560-32-3(Hazardous Substances Data)

Usage

Type of compound

brominated derivative of anthracenone

Usage

building block in the synthesis of various organic compounds and pharmaceuticals

Physical appearance

yellow crystalline

Solubility

insoluble in water

Primary use

intermediate in the production of dyes, pigments, and fluorescent materials

Additional use

organic synthesis and as a reagent in various chemical reactions

Potential applications

research and medicinal applications due to its chemical and biological properties

InChI:InChI=1/C14H9BrO/c15-13-9-5-1-3-7-11(9)14(16)12-8-4-2-6-10(12)13/h1-8,13H

Upstream product

• 529-86-2 9-anthrol 
• 90-44-8 anthracen-9(10H)-one 
• 4741-24-6 9,10-epidioxy-9,10-dihydroanthracene 
• 10035-10-6 hydrogen bromide 
• 549-99-5 oxanthrone 
• 7726-95-6 bromine 
• 123-91-1 1,4-dioxane 
• 120-12-7 anthracene 
• 7732-18-5 water 
• 5954-04-1 anthracen-9-yl phenylacetate 
• 64-19-7 acetic acid 
• 1564-64-3 9-Bromoanthracene 

Downstream Products

• 90-44-8 anthracen-9(10H)-one 
• 434-84-4 bianthronyl 
• 84-65-1 9,10-phenanthrenequinone 
• 100770-94-3 anthrol bue 
• 127479-07-6 10-benzoyloxy-anthrone 
• 434-85-5 bianthrone 
• 22219-68-7 3'-phenyl-spiro[anthracen-9,2'-oxiran]-10-one 
• 740837-78-9 10-anilino-anthrone 
• 27761-50-8 10-phenylhydrazono-9,10-dihydroanthracen-9-one 
• 57374-15-9 acetic acid-(10-p-tolyl-[9]anthryl ester) 
• 14596-70-4 10-phenylanthrone 
• 105285-52-7 9-Phenyl-10-prop-2-ynyloxy-anthracene 
• 105285-44-7 9-allyloxy-10-phenylanthracene 
• 105285-45-8 9-(2-Chloro-allyloxy)-10-phenyl-anthracene 

Relevant articles and documents

Aromatic hydroxylation of anthracene derivatives by a chromium(III)-superoxo complex via proton-coupled electron transfer

The chemistry of metal-superoxo intermediates started being unveiled in oxidation reactions by enzymes and their synthetic model compounds. However, aromatic hydroxylation reactions by the metal-superoxo species are yet to be demonstrated. In this study, we report for the first time that the hydroxylation of aromatic compounds such as anthracene and its derivatives by a mononuclear nonheme Cr(iii)-superoxo complex, [(Cl)(TMC)CrIII(O2)]+ (1), occurs in the presence of triflic acid (HOTf) via the rate-determining proton-coupled electron transfer (PCET) from anthracene to 1, followed by a fast further oxidation to give anthraquinone. The rate constants of electron transfer from anthracene derivatives to 1 in the presence of HOTf are well analyzed in light of the Marcus theory of electron transfer.

NEW AND RENEWED SYNTHESES OF 10-PHENYLANTHRONE AND 10-HYDROXY-10-PHENYLANTHRONE

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Aloin, some observations on its constitution.

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