Tetrahedron Letters p. 3833 - 3836 (1988)
Update date:2022-08-11
Topics:
Kondo, Teruyuki
Tsuji, Yasushi
Watanabe, Yoshihisa
Various transition metal complexes including group VII and VIII metal carbonyls are highly active catalyst precursors for the photochemical carbonylation of organic iodides at room temperature under an atmospheric pressure of carbon monoxide.Primary, secondary and tertiary alkyl iodides which have β-hydrogens on sp3-carbons were smoothly carbonylated by this catalyst system without β-hydride elimination to give the corresponding esters in yields of 63 - 88 percent.
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