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Oxo(phosphine)ruthenium(IV) Redox Chemistry: Substrate Oxidation Selectivity Based on Substrate Hydrophobicity

DOI: 10.1039/c39870001396

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1396 - 1397 (1987)

Update date:2022-08-17

Topics:

Authors:

Marmion, Mary E.Marmion, Mary E.

Takeuchi, Kenneth J.Takeuchi, Kenneth J.

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Article abstract of DOI:10.1039/c39870001396

The oxidation of primary alcohols by oxo(phosphine)ruthenium(IV) complexes is shown to display a unique hydrophobic selectivity, on the basis of the dependence of the oxidation rate constant on alcohol hydrophobicity, phosphine hydrophobicity, and solvent.

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