Journal of Physical Chemistry p. 478 - 483 (1980)
Update date:2022-08-11
Topics:
Takagi, H.
Washida, N.
Akimoto, H.
Nagasawa, K.
Ususi, Y.
Okuda, M.
The reaction products in the photooxidation of o-xylene were analyzed by a new gas chromatograph/photoionization mass spectrometer.There were two types of reaction products, i.e., high- and low-boiling point products.Tolualdehyde, dimethylphenols, and dimethylnitrobenzene were the main high-boiling point products and formaldehyde, acetaldehyde, glyoxal, methylglyoxal, and biacetyl were identified as low-boiling point products.The ratio of the total amount of high-boiling point products formed to the amount of o-xylene consumed was about 17percent.On the other hand, the low-boiling point products collected amounted to about 45percent of the o-xylene consumed.The reaction mechanisms and the importance of the cleavage reaction of the aromatic ring were discussed.
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Doi:10.1163/157180800X00163
(1885)Doi:10.1039/P29810000825
(1981)Doi:10.1016/S0968-0896(97)00054-0
(1997)Doi:10.1016/S0040-4039(98)02090-5
(1998)Doi:10.1021/ja511329m
(2015)Doi:10.1016/S0960-894X(00)00450-9
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