Ru(III) CATALYSIS IN OXIDATION OF n-PROPANOL AND n-BUTANOL BY ACIDIC SOLUTIONS OF BROMAMINE-T

DOI: 10.1016/S0040-4020(01)91271-2

Source and publish data:

Tetrahedron p. 5203 - 5206 (1984)

Update date:2022-08-11

Topics:

Authors:

Singh, Bharat

Singh, A. K.

Singh, N. B.

Saxena, B. B. L.

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Article abstract of DOI:10.1016/S0040-4020(01)91271-2

Kinetics of Ru(III) catalysed oxidation of n-propanol and n-butanol by acidic solutions of bromamine-T have been investigated.The results show that oxidation of both alcohols follows first-order kinetics in bromamine-T, both alcohols, hydrogen ion concentration and Ru(III).Decreasing effect of variation on reaction rate was observed.No effect of p-toluenesulphonamide and ionic strength of the medium was observed.Activation parameters have been calculted and recorded.A suitable mechanism in conformity with the above observations has been proposed.

Full text of DOI:10.1016/S0040-4020(01)91271-2

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