Inorganica Chimica Acta p. 125 - 130 (2017)
Update date:2022-08-11
Topics:
Vargas, Diana Gabriela
Metta-Maga?a, Alejandro
Sharma, Hemant K.
Whalen, Margaret M.
Gilbert, Thomas M.
Pannell, Keith H.
The tetravalent organotin compound [MeS(CH2)3]2SnCl2, 1, has been synthesized in high yield and structurally characterized as being hexa-coordinate at tin with two intramolecular Sn-S bonds. The specific structure has been shown by theoretical calculations to be the low energy geometric structure available, and the differences associated with the experimental and calculated Sn-S bond lengths ascribed to crystal packing issues. The intramolecular Sn-S bonding produces a benign organotin compound with respect to its interactions with human natural killer cells; however, this blocking of coordination sites at Sn does not reduce its capacity to act as an efficient esterification catalyst.
View MoreShanghai Bojing Chemical Co., Ltd.
Contact:021-37122233
Address:6F Buildiing 11,No.388,Baifu Road,District Fengxian.Shanghai, China.
Shanghai Yurui Biotechnology(Anyang) Pharmaceutical Co., Ltd
Contact:+86-0372-3662335 +86-0372-3661988
Address:hanling industrial park anyang
Hangzhou yi lu biont technology Co., LTD
Contact:+86-571-88152630
Address:Hangzhoushi HuafengRoad Yicheng3Building1001room.
Hangzhou Think Chemical Co. Ltd
website:http://www.thinkchem.com/
Contact:86-571-89986307/81956191/81956084/81956192
Address:Room 501-502, Tower E, Yuanjian Building, Yuanyang International Center, Hangzhou-310011, China
Contact:0512-63006287
Address:no.88.YISHENG Road,etdz-WUJIANG,SUZHOU,CHINA
Doi:10.1080/00397919808005711
(1998)Doi:10.1016/j.tet.2005.05.007
(2005)Doi:10.1016/S0040-4039(97)01084-8
(1998)Doi:10.1016/0040-4039(96)00011-1
(1996)Doi:10.1016/j.molcatb.2014.10.015
(2015)Doi:10.1016/S0040-4039(01)82306-6
(1974)