Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 468 - 472 (1989)
Update date:2022-08-12
Topics:
Sharf, V. Z.
Dovganyuk, V. F.
Isaeva, V. I.
Maksimov, B. I.
Rh complexes attached to modified silica gels catalyze the reaction of hydrogen transfer from 2-propanol (P-2) to cyclohexanone, styrene, allylbenzene, and cyclohexene-2-one.It was previously found <2> that triphenylphosphine complexes of Rh and Ru are active in the reaction of reduction of nitrobenzene (NB) by 2-propanol.It is known that complex hydrides, NaBH4 in particular, are also used for reduction of NB on metal complexes.The catalytic properties of Rh complexes immobilized on silica gels containing amino groups and aminophosphine groups in reduction of NB and different halonitrobenzenes by transfer of hydrogen from P-2 and NaBH4 were investigated in the present study.
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