Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 468 - 472 (1989)
Update date:2022-08-12
Topics:
Sharf, V. Z.
Dovganyuk, V. F.
Isaeva, V. I.
Maksimov, B. I.
Rh complexes attached to modified silica gels catalyze the reaction of hydrogen transfer from 2-propanol (P-2) to cyclohexanone, styrene, allylbenzene, and cyclohexene-2-one.It was previously found <2> that triphenylphosphine complexes of Rh and Ru are active in the reaction of reduction of nitrobenzene (NB) by 2-propanol.It is known that complex hydrides, NaBH4 in particular, are also used for reduction of NB on metal complexes.The catalytic properties of Rh complexes immobilized on silica gels containing amino groups and aminophosphine groups in reduction of NB and different halonitrobenzenes by transfer of hydrogen from P-2 and NaBH4 were investigated in the present study.
View More
Beijing Mediking Biopharm Co., Ltd.
Contact:+86-10-89753524/81760121/81769521
Address:Hongxianghong Incubator, Beiqijia Town, Changping district, Beijing, China
Contact:86-571-61063068
Address:LINAN
Shandong Yuanli Science and Technology Co., Ltd.
Contact:86-0536-6777557
Address:Zhuliu Industiral Park,Changle County
Tai zhou world Pharm & Chem Co., Ltd
Contact:+86-576-85301198
Address:Rome 1001,wangjiang plaza,unti 2,jinshan east Road linhai,zhejiang,china
Contact:
Address:308# dongwu avenue dongxihu district wuhan city
Doi:10.1016/0039-128X(66)90104-8
(1966)Doi:10.1021/bi301059m
(2012)Doi:10.1021/j100156a038
(1991)Doi:10.1007/BF00472629
(1989)Doi:10.1016/j.tetasy.2005.10.009
(2005)Doi:10.1038/s41429-018-0076-5
(2018)
