Journal of the Chemical Society. Chemical communications p. 161 - 163 (1989)
Update date:2022-08-31
Topics:
Ibrahim, Sani
Watt, C. Ian F.
Wilson, John M.
Moore, Colin
Primary and secondary kinetic hydrogen isotope effects (k.i.e.s) in the elimination of toluene from the alkoxide of 1,2,3-triphenylpropane-2-ol have been determined and are consistent with rate limiting proton transfer in gas phase reaction and with rate limiting carbon-carbon bond cleavage in reaction in dimethyl sulphoxide (DMSO) solution.
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