Journal of Organometallic Chemistry p. C11 - C13 (1983)
Update date:2022-08-11
Topics:
Besace, Y.
Berlan, J.
Pourcelot, G.
Huche, M.
In diastereoselective addition of methylcopper and dimethylcuprate to a chiral α-β-ethylenic oxazolidine in Et2O or THF, 3-(S)-phenylbutanal is formed with (ee) in the range of 30 to 50percent.Use of apolar solvents like hexane gives an inversion of configuration and an increase of the enantiomeric excess up to 80percent.
View More
Contact:13357117572
Address:No.149 Shiji dadao Road.
Shanghai Egoal Chemical Co.,Ltd
Contact:+86-21-50333091
Address:Yangming Garden Square 3,YangGao North Road 1188, Pudong New District, Shanghai
Wuhan Sunrise Pharmaceutical Technology Co., Ltd
Contact:+86-27-83314682
Address:Room 340, New material Industrial base No.17, Gu Tian Five Lu , Qiaokou District, Wuhan , China
HANGZHOU TOYOND BIOTECH CO., LTD
Contact:+86-571-86965177
Address:No. 189, Fengqi East Road, Hangzhou, China
Contact:+86-10-67147360/67107388
Address:No.18 Guangming Zhongjie, Chongwen District, Beijing, 100061, China
Doi:10.1055/s-1998-1848
(1998)Doi:10.1016/0040-4039(95)01984-P
(1995)Doi:10.1039/c4dt00551a
(2014)Doi:10.1002/anie.202003886
(2020)Doi:10.1039/jr9580003018
(1958)Doi:10.1016/S0040-4039(01)94169-3
(1972)
