Tetrahedron Letters p. 4685 - 4688 (1994)
Update date:2022-08-11
Topics:
Xu, Daqiang
Sharpless, K. Barry
Goniobutenolides A and B and their C-7 epimers are stereoselectively synthesized using osmium-catalyzed asymmetric dihydroxylation (AD) as the key transformation. The relative and absolute stereochemistry of the natural goniobutenolides A and B are assigned with reference to the spectral data and optical rotations from the literature.
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