Tetrahedron p. 5089 - 5094 (1987)
Update date:2022-08-16
Topics:
Wilen, Samuel H.
Delguzzo, Luciano
Saferstein, Richard
The reaction of diol diacetates with anhydrous aluminium chloride at ca 100° leads to displacement of only one of the acetoxy groups by chlorine. An oxygen-18 label study has shown that these displacements take place via acetoxonium intermediates and has provided direct evidence for the intervention of a seven-membered ring acetoxonium ion in the displacement of acetate by chlorine in 1,4-butanediol diacetate.
View More
Beijing Wisdom Chemicals Co., Ltd.
Contact:+86-10-52350335
Address:F2, BLDG 19, Liando Valley U, Majuqiao, Tongzhou District, Beijing, China
Contact:0086-27-83607103/83642615
Address:No.498, Jianshe Ave, Wuhan, China
Contact:+86-15995924277
Address:WuZhongOu suzhou new south road 89
Quzhou Aokai Chemical Co., Ltd.
Contact:86-570-3032832
Address:NO.16 , Laodong Road,Quzhou City, Zhejiang Province,China
Shenzhen ZheYi Chemicals Co.,LTD(Shanghai Branch)
Contact:+86-21-54159691
Address:Room1002,Building No.2, Lane 98 Bixiu Road,Minhang District, Shanghai,China 201100
Doi:10.1021/j100130a016
(1993)Doi:10.1016/0013-4686(89)87120-8
(1989)Doi:10.1016/j.elspec.2006.11.030
(2007)Doi:10.1016/S0040-4039(00)87540-1
(1982)Doi:10.1039/c4cy00021h
(2014)Doi:10.1021/ja00528a062
(1980)
