Journal of Physical Chemistry p. 3435 - 3438 (1985)
Update date:2022-08-16
Topics:
Wlodek, S.
Wincel, H.
A mechanism for the gas-phase nucleophilic displacement reaction, NO2(1-) + C2H5ONO2 --> NO3(1-) + C2H5ONO, has been postulated on the basis of the calculated stabilities of the (NO2(1-)*C2H5ONO2) complex.The potential-energy diagram for the reaction pathway is characterized by three minima.The relative yield of NO3(1-) in mixtures with various bath gases has been examined with high-pressure mass spectrometry.The results indicate that the efficiency of NO3(1-) production depends upon the nature of the third body.
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