Stereoselective Total Synthesis of (+/-)-Aristolactone and (+/-)-Epiaristolactone via (2,3) Wittig Ring Contraction

DOI: 10.1021/jo00226a031

Source and publish data:

Journal of Organic Chemistry p. 3883 - 3889 (1987)

Update date:2022-08-11

Topics:

Authors:

Marshall, James A.

Lebreton, Jacques

DeHoff, Bradley S.

Jenson, Todd M.

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Article abstract of DOI:10.1021/jo00226a031

The germacranolide bridged lactone aristolactone (16) has been synthesized starting from geranyl acetate.Homologation of derived chloride 5 via coupling with <(triisopropylsilyl)propargyl>magnesium bromide followed by deprotection, metalation and addition

Full text of DOI:10.1021/jo00226a031

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