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Alkyne Insertion into Ruthenium-Carbon Bonds: Formation and Ring-closing Reactions of Vinyl Complexes

DOI: 10.1039/DT9890000465

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 465 - 470 (1989)

Update date:2022-08-11

Topics:

Authors:

Crook, Joseph R.Crook, Joseph R.

Chamberlain, BarbaraChamberlain, Barbara

Mawby, Roger J.Mawby, Roger J.

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Article abstract of DOI:10.1039/DT9890000465

Compounds <(1a), X=H; (1b), X=Cl; (1c), X=Me; (1d), X=OMe> react with to yield vinyl complexes (2a)-(2d).The mechanism of formation appears to involve CO substitution by the alkyne, combination of alkyne a

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